Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17 Page 18 Page 19 Page 20 Page 21 Page 22 Page 23 Page 24 Page 25 Page 26 Page 27 Page 28 Page 29 Page 30 Page 31 Page 32 Page 33 Page 34 Page 35 Page 36 Page 37 Page 38 Page 39 Page 40 Page 41 Page 42 Page 43 Page 44 Page 45 Page 46 Page 47 Page 48 Page 49 Page 50 Page 51 Page 52 Page 53 Page 54 Page 55 Page 56 Page 57 Page 58 Page 59 Page 60 Page 61 Page 62 Page 63 Page 64 Page 65 Page 66 Page 67 Page 68 Page 69 Page 70 Page 71 Page 72 Page 73 Page 74 Page 75 Page 76 Page 77 Page 78 Page 79 Page 80 Page 81 Page 82 Page 83 Page 84 Page 85 Page 86 Page 87 Page 88 Page 89 Page 90 Page 91 Page 92 Page 93 Page 94 Page 95 Page 96 Page 97 Page 98 Page 99 Page 100 Page 101 Page 102 Page 103 Page 104 Page 105 Page 106 Page 107 Page 108 Page 109 Page 110 Page 111 Page 112 Page 113 Page 114 Page 115 Page 116 Page 117 Page 118 Page 119 Page 120 Page 121 Page 122 Page 123 Page 124 Page 125 Page 126 Page 127 Page 128 Page 129 Page 130 Page 131 Page 132 Page 133 Page 134 Page 135 Page 136 Page 137 Page 138 Page 139 Page 140 Page 141 Page 142 Page 143 Page 144 Page 145 Page 146 Page 147 Page 148 Page 149 Page 150 Page 151 Page 152 Page 153 Page 154 Page 155 Page 156 Page 157 Page 158 Page 159 Page 160 Page 161 Page 162 Page 163 Page 164 Page 165 Page 166 Page 167 Page 168 Page 169 Page 170 Page 171 Page 172 Page 173 Page 174 Page 175 Page 176 Page 177 Page 178 Page 179 Page 180 Page 181 Page 182 Page 183 Page 184 Page 185 Page 186 Page 187 Page 188 Page 189 Page 190 Page 191 Page 192 Page 193 Page 194 Page 195 Page 196 Page 197 Page 198 Page 199 Page 200 Page 201 Page 202 Page 203 Page 204 Page 205 Page 206 Page 207 Page 208 Page 209 Page 210 Page 211 Page 212 Page 213 Page 214 Page 215 Page 216 Page 217 Page 218 Page 219 Page 220 Page 221 Page 222 Page 223 Page 224 Page 225 Page 226 Page 227 Page 228 Page 229 Page 230 Page 231 Page 232 Page 233 Page 234 Page 235 Page 236 Page 237 Page 238 Page 239 Page 240 Page 241 Page 2422016 | AFC ACCOMPLISHMENTS 48 materials contained Iron, it is believed these elements come from the second phase particles in the Zircaloy-2. Porosity was observed within the CrAl film beneath the alumina layer.The pores did not cause delamination and is believed that diffusion of Aluminum into the Zircaloy-2 substrate, forming the intermetallic phase, improves adhesion. Coated and uncoated Zircaloy were exposed to normal operating water chemistry at University of Michigan (U of M) for 10 and 20 days.Addi- tionally, one of the 10 day exposed samples was oxidized at 700C for 3.5 hours in steam at UIUC. Char- acterization by SEM/EDS, XRD, and TEM found that the FeCrAl coated promoted the growth of an iron- nickel spinel from ions leached from the autoclave system.This surface feature did not affect the protective nature of the base FeCrAl coating. No change in kinetics was seen as compared to as grown samples. Post oxidation characterization revealed that although the spinel persisted through the exposure, normal alpha- alumina formation occurred beneath it.The porosity within the FeCrAl layer is thought to be caused by the clustering of the counter flow of vacancies in response to the outward diffusion of Al ions.As grown FeCrAl coatings were irradiated with protons and iron at U of M.TEM analysis of the irradiated samples is ongoing at UIUC with no substantial detrimental effects observed so far.Analysis of subsequent autoclave exposed irradi- ated samples is occurring at U of M. Diffraction studies of high tempera- Figure 2. X-ray diffraction patterns of CrAl coatings on Zircaloy-2 after exposure in 700C steam environment for 20 hours. The numbers on each pattern show the atomic percentage of the Aluminum of the as-grown CrAl coatings. ZrO2 did not form on the 1um CrAl coated Zircaloy-2.