Page 1 Page 2 Page 3 Page 4 Page 5 Page 6 Page 7 Page 8 Page 9 Page 10 Page 11 Page 12 Page 13 Page 14 Page 15 Page 16 Page 17 Page 18 Page 19 Page 20 Page 21 Page 22 Page 23 Page 24 Page 25 Page 26 Page 27 Page 28 Page 29 Page 30 Page 31 Page 32 Page 33 Page 34 Page 35 Page 36 Page 37 Page 38 Page 39 Page 40 Page 41 Page 42 Page 43 Page 44 Page 45 Page 46 Page 47 Page 48 Page 49 Page 50 Page 51 Page 52 Page 53 Page 54 Page 55 Page 56 Page 57 Page 58 Page 59 Page 60 Page 61 Page 62 Page 63 Page 64 Page 65 Page 66 Page 67 Page 68 Page 69 Page 70 Page 71 Page 72 Page 73 Page 74 Page 75 Page 76 Page 77 Page 78 Page 79 Page 80 Page 81 Page 82 Page 83 Page 84 Page 85 Page 86 Page 87 Page 88 Page 89 Page 90 Page 91 Page 92 Page 93 Page 94 Page 95 Page 96 Page 97 Page 98 Page 99 Page 100 Page 101 Page 102 Page 103 Page 104 Page 105 Page 106 Page 107 Page 108 Page 109 Page 110 Page 111 Page 112 Page 113 Page 114 Page 115 Page 116 Page 117 Page 118 Page 119 Page 120 Page 121 Page 122 Page 123 Page 124 Page 125 Page 126 Page 127 Page 128 Page 129 Page 130 Page 131 Page 132 Page 133 Page 134 Page 135 Page 136 Page 137 Page 138 Page 139 Page 140 Page 141 Page 142 Page 143 Page 144 Page 145 Page 146 Page 147 Page 148 Page 149 Page 150 Page 151 Page 152 Page 153 Page 154 Page 155 Page 156 Page 157 Page 158 Page 159 Page 160 Page 161 Page 162 Page 163 Page 164 Page 165 Page 166 Page 167 Page 168 Page 169 Page 170 Page 171 Page 172 Page 173 Page 174 Page 175 Page 176 Page 177 Page 178 Page 179 Page 180 Page 181 Page 182 Page 183 Page 184 Page 185 Page 186 Page 187 Page 188 Page 189 Page 190 Page 191 Page 192 Page 193 Page 194 Page 195 Page 196 Page 197 Page 198 Page 199 Page 200 Page 201 Page 202 Page 203 Page 204 Page 205 Page 206 Page 207 Page 208 Page 209 Page 210 Page 211 Page 212 Page 213 Page 214 Page 215 Page 216 Page 217 Page 218 Page 219 Page 220 Page 221 Page 222 Page 223 Page 224 Page 225 Page 226 Page 227 Page 228 Page 229 Page 230 Page 231 Page 232 Page 233 Page 234 Page 235 Page 236 Page 237 Page 238 Page 239 Page 240 Page 241 Page 2422016 | AFC ACCOMPLISHMENTS 47 Project Description: The efficacy of FeCrAl coatings relies on several factors.The main focus is the identification of a range FeCrAl compositions which exhibit optimum oxidation resistance when deposited to thicknesses on the order of microns on Zircaloy.This work encapsulated the coating growth, adherence, and performance in high temperature steam. Extensive characterization of the coating, and coating-clad interactions during each step of this processes through the use of XRD, SEM,TEM, and AES garnered in-depth understanding of the physical mecha- nisms present in each stage.With this knowledge, a single composition was selected for exposure to normal operating conditions as well as proton and heavy ion irradiation to confirm the coatings reliability during stan- dard operation. Modeling the effects of the coating was coupled with experimental results to understand the thermal and neutronic effects of this new layer on the reactor.The neutronics analysis ties strongly into the selection of a composition by informing how the neutron popula- tion, and therefore fuel lifetime is effected by the atomic ratios, as well as coating thickness.The experimental and computational results regarding this new parameter space provides key information needed for an economi- cally informed selection of a composi- tion from the identified safe ranges. Additional experimental research into the high temperature steam oxidation of binary alloys was conducted to further enhance our knowledge of the behavior our current alloys in accident scenarios.Alternative CrAl and Cr coatings have also been investigated. Accomplishments: At the University of Illinois Urbana/ Champaign (UIUC) Chromium- Aluminum and Chromium coatings on Zircaloy-2 with thicknesses of about 1um were exposed to 700C steam for up to 20 hours. No Zirco- nium oxide formed on the CrAl coated Zircaloy whereas ZrO2 with the thickness of over 100um is expected to form on the uncoated Zircaloy and some was observed on the Cr coated Zircaloy-2. For CrAl coatings, (Cr,Al)2O3 formed on the CrAl film with Al compsition of 19 atomic percentage. Higher Al compositions did not grow thick enough oxides for resolvable XRD peaks, however STEM confirmed a 65nm thick Al2O3 layer. In addition, an intermetallic layer was observed between the CrAl coating and Zircaloy and was indexed as Zr6FeAl2 by XRD.As neither the exposed environment nor coatings CrAl coating with the thickness of 1um inhibited the oxidation of Zircaloy substrate for over 20 hours at 700C steam environment, while over 100um ZrO2 is expected to form on the uncoated Zircaloy.